JEE Advanced Chemistry Syllabus 2019 – Get PDF Here for Free

JEE Advanced Chemistry Syllabus 2019 has been released. Here we are mentioning the complete JEE Advanced Chemistry Syllabus.

JEE Advanced Syllabus- PDF Available

NewJEE Advanced Chemistry Syllabus has been released. Click Here to Download the PDF.

JEE Advanced Chemistry Syllabus

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Physical Chemistry

GeneralThe concept of atoms and molecules; Dalton’s atomic theory; Mole concept; Chemical formulae; Balanced chemical equations; Calculations (based on mole concept) involving common oxidation-reduction, neutralization, and displacement reactions; Concentration regarding mole fraction, molarity, molality, and normality.
Gaseous and Liquid StatesThe absolute scale of temperature, ideal gas equation; Deviation from ideality, van der Waals equation; Kinetic theory of gases, average, root mean square and most probable velocities and their relation with temperature; Law of partial pressures; Vapour pressure; Diffusion of gases.
Atomic structure and chemical bondingBohr model, the spectrum of hydrogen atom, quantum numbers; Wave-particle duality, de Broglie hypothesis; Uncertainty principle; Qualitative quantum mechanical picture of a hydrogen atom, shapes of s, p and d orbitals; Electronic configurations of elements (up to atomic number 36);

Aufbau principle; Pauli’s exclusion principle and Hund’s rule; Orbital overlap and covalent bond; Hybridisation involving s, p and d orbitals only; Orbital energy diagrams for homonuclear diatomic species; Hydrogen bond; Polarity in molecules, dipole moment (qualitative aspects only); VSEPR model and shapes of molecules (linear, angular, triangular, square planar, pyramidal, square pyramidal, trigonal bipyramidal, tetrahedral and octahedral).

EnergeticsFirst law of thermodynamics; Internal energy, work, and heat, pressure-volume work; Enthalpy, Hess’s law; Heat of reaction, fusion, and vapourization; Second law of thermodynamics; Entropy; Free energy; Criterion of spontaneity.
Chemical EquilibriumLaw of mass action; Equilibrium constant, Le Chatelier’s principle (effect of concentration, temperature, and pressure); Significance of AG and AG0 in chemical equilibrium; Solubility product, common ion effect, pH and buffer solutions; Acids and bases (Bronsted and Lewis concepts); Hydrolysis of salts.
Electro-ChemistryElectrochemical cells and cell reactions; Standard electrode potentials; Nernst equation and its relation to AG; Electrochemical series, emf of galvanic cells; Faraday’s laws of electrolysis; Electrolytic conductance, specific, equivalent and molar conductivity, Kohlrausch’s law; Concentration cells.
Chemical KineticsRates of chemical reactions; Order of reactions; Rate constant; First order reactions; Temperature dependence of rate constant (Arrhenius equation).
Solid StateClassification of solids, crystalline state, seven crystal systems (cell parameters a, b, c, a, P, Y), close-packed structure of solids (cubic), packing in fcc, bcc and hcp lattices; Nearest neighbors, ionic radii, simple ionic compounds, point defects.
SolutionsRaoult’s law; Molecular weight determination from lowering of vapor pressure, elevation of boiling point and depression of freezing point.
Surface ChemistryElementary concepts of adsorption (excluding adsorption isotherms); Colloids: types, methods of preparation and general properties; Elementary ideas of emulsions, surfactants and micelles (only definitions and examples).
Nuclear ChemistryRadioactivity: isotopes and isobars; Properties of a, P and Y rays; Kinetics of radioactive decay (decay series excluded), carbon dating; Stability of nuclei with respect to proton-neutron ratio; Brief discussion on fission and fusion reactions.

 

Organic chemistry

ConceptsThe hybridization of carbon; o and n-bonds; Shapes of simple organic molecules; Structural and geometrical isomerism; Optical isomerism of compounds containing up to two asymmetric centers, (R, S, and E, Z nomenclature excluded);

 

IUPAC nomenclature of simple organic compounds (only hydrocarbons, mono-functional, and bi-functional compounds); Conformations of ethane and butane (Newman projections); Resonance and hyperconjugation; Keto-enol tautomerism;

 

Determination of empirical and molecular formulae of pure compounds (only combustion method);

Hydrogen bonds: definition and their effects on the physical properties of alcohols and carboxylic acids; Inductive and resonance effects on acidity and basicity of organic acids and bases;

 

Polarity and inductive effects in alkyl halides; Reactive intermediates produced during homolytic and heterolytic bond cleavage; Formation, structure and stability of carbocations, carbanions and free radicals.

Preparation, Properties, and Reactions of AlkanesHomologous series, physical properties of alkanes (melting points, boiling points, and density); Combustion and halogenation of alkanes; Preparation of alkanes by Wurtz reaction and decarboxylation reactions.
Preparation, Properties, And Reactions Of Alkenes And AlkynesPhysical properties of alkenes and alkynes (boiling points, density and dipole moments); Acidity of alkynes; Acid catalyzed hydration of alkenes and alkynes (excluding the stereochemistry of addition and elimination); Reactions of alkenes with KMnO4 and ozone;

 

Reduction of alkenes and alkynes; Preparation of alkenes and alkynes by elimination reactions; Electrophilic addition reactions of alkenes with X2, HX, HOX and H2O (X=halogen); Addition reactions of alkynes; Metal acetylides.

Reactions of benzeneStructure and aromaticity; Electrophilic substitution reactions: halogenation, nitration, sulphonation, Friedel-Crafts alkylation, and acylation; Effect of o-, m- and ^-directing groups in monosubstituted benzenes.
PhenolsAcidity, electrophilic substitution reactions (halogenation, nitration, and sulphonation); Reimer-Tieman reaction, Kolbe reaction.
Characteristic reactions of the following (including those mentioned above)Alkyl halides: rearrangement reactions of alkyl carbocation, Grignard reactions, nucleophilic substitution reactions; Alcohols: esterification, dehydration and oxidation, reaction with sodium, phosphorus halides,

 

ZnCl2/concentrated HCl, conversion of alcohols into aldehydes and ketones; Ethers:

Preparation by Williamson’s Synthesis; Aldehydes and Ketones: oxidation, reduction, oxime and hydrazone formation; aldol condensation, Perkin reaction; Cannizzaro reaction; haloform reaction and nucleophilic addition reactions (Grignard addition);

Carboxylic acids: formation of esters,

 

acid chlorides and amides, ester hydrolysis; Amines: basicity of substituted anilines and aliphatic amines, preparation from nitro compounds, reaction with nitrous acid, the azo coupling reaction of diazonium salts of aromatic amines,

Sandmeyer and related reactions of diazonium salts; carbylamine reaction; Haloarenes: nucleophilic aromatic substitution in haloarenes and substituted haloarenes (excluding Benzyne mechanism and Cine substitution).

CarbohydratesClassification; mono- and di-saccharides (glucose and sucrose); Oxidation, reduction, glycoside formation and hydrolysis of sucrose.
Amino acids and peptidesGeneral structure (only primary structure for peptides) and physical properties.
Properties and uses of some important polymersNatural rubber, cellulose, nylon, Teflon, and PVC.
Practical Organic ChemistryDetection of elements (N, S, halogens); Detection and identification of the following functional groups: hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl, amino, and nitro; Chemical methods of separation of mono¬functional organic compounds from binary mixtures.

 

Inorganic chemistry

Isolation/preparation and properties of the following non-metalsBoron, silicon, nitrogen, phosphorus, oxygen, sulfur, and halogens; Properties of allotropes of carbon (only diamond and graphite), phosphorus and sulfur.
Preparation and properties of the following compoundsOxides, peroxides, hydroxides, carbonates, bicarbonates, chlorides and sulphates of sodium, potassium, magnesium and calcium; Boron: diborane, boric acid and borax; Aluminium: alumina, aluminium chloride and alums; Carbon: oxides and oxyacid (carbonic acid); Silicon: silicones, silicates and silicon carbide; Nitrogen: oxides, oxyacids and ammonia; Phosphorus: oxides, oxyacids (phosphorus acid, phosphoric acid) and phosphine;

Oxygen: ozone and hydrogen peroxide; Sulphur: hydrogen sulfide, oxides, sulfurous acid, sulphuric acid, and sodium thiosulphate; Halogens: hydrohalic acids, oxides, and oxyacids of chlorine, bleaching powder; Xenon fluorides.

Transition elements (3d series)Definition, general characteristics, oxidation states, and their stabilities, color (excluding the details of electronic transitions) and calculation of spin-only magnetic moment; Coordination compounds: nomenclature of mononuclear coordination compounds, cis-trans, and ionization isomerisms, hybridization and geometries of mononuclear coordination compounds (linear, tetrahedral, square planar and octahedral).
Preparation and properties of the following compoundsOxides and chlorides of tin and lead;

Oxides, chlorides, and sulfates of Fe2+, Cu2+and Zn2+;

Potassium permanganate, potassium dichromate, silver oxide, silver nitrate, silver thiosulphate.

Ores and mineralsCommonly occurring ores and minerals of iron, copper, tin, lead, magnesium, aluminum, zinc and silver.
Extractive metallurgyChemical principles and reactions only (industrial details excluded); Carbon reduction method (iron and tin); Self reduction method (copper and lead); Electrolytic reduction method (magnesium and aluminum); Cyanide process (silver and gold).
Principles Of Qualitative AnalysisGroups I to V (only Ag+, Hg2+, Cu2+, Pb2+, Bi3+, Fe3+, Cr3+, Al3+, Ca2+, Ba2+, Zn2 2+ 2+

Mn and Mg ); Nitrate, halides (excluding fluoride), sulfate and sulfide.

 

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